Dibromido{2-[2-(piperidinium-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate
نویسندگان
چکیده
The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol-ecule and a solvent water mol-ecule. The Zn(II) atom is four-coordinated in an approximately tetra-hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(-) anions. In the crystal structure, mol-ecules are linked through inter-molecular O-H⋯Br and O-H⋯O hydrogen bonds, forming chains running along the b axis.
منابع مشابه
{2-Ethoxy-6-[2-(piperidinium-1-yl)ethyliminomethyl]phenolato}diiodidozinc(II)
The title Schiff base complex, [ZnI(2)(C(16)H(24)N(2)O(2))], is a mononuclear zinc(II) compound. The Zn atom is four-coordinated in a distorted tetra-hedral geometry by one phenolate O atom and one imine N atom of the Schiff base ligand and by two iodide ions. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the a axis.
متن کاملDichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate
In the title mononuclear zinc(II) complex, [ZnCl(2)(C(14)H(20)N(2)O)]·H(2)O, the Zn(II) atom is four-coordinated by the phenolate O and imine N atoms of the Schiff base ligand and by two Cl atoms in a tetra-hedral geometry. In the crystal structure, O-H⋯Cl, O-H⋯O and N-H⋯O hydrogen bonds involving the water mol-ecules bridge adjacent complexes into a ladder-like structure running along the c axis.
متن کاملBis{4-chloro-2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}zinc(II)
The Zn atom in the title compound, [Zn(C(17)H(14)ClN(2)O)(2)], is N,O-chelated by two deprotonated Schiff base monoanionic ligands in a tetra-hedral coordination geometry. The Zn atom lies on a special position of site symmetry 2.
متن کاملDiiodido{4-nitro-2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II)
In the title complex, [ZnI(2)(C(14)H(19)N(3)O(3))], the Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming dimers.
متن کاملBis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate
The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H⋯O hydrogen bond.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008